Several key flaws here, the first being pointed out already. A person will produce 40g/hr of CO2 by these figures, while resting. Figure they drive at 60km/h, for convenience. Then they produce 4g of CO2 on top of the car. Since the claim was made on such a small difference, this makes the car-human system produce 103g/km at 60km/h in a VW Polo 1.4L versus 100g/km with human running.
Second, the 100g/km figure is not accurate enough. It implies 1 significant figure. It is accurate enough to say that a human runner should produce between 50 and 150g/km, but not exact enough to say it is 100, not 98, which would give the runner the advantage over the VW.
Third, the car chosen is an extremly low carbon output vehicle. I believe a Toyota Prius is a little higher, around 105g/km. If the US views that as a green car, then clearly the average US vehicle will produce far more. Some of our SUVs produce over 300g/km. Most cars are high 100s, low 200s. Further, only the newest vehicles can be under ~150. Anything more than say 6 years old will be far worse than these example vehicles. I'm sure my '95 with a 2.5L V6 produces far more carbon than the '08 2.5L Inline 5 my father has.
My general opinion of people in the news, celebrities, etc is usually true (hence why it's my "general" opinion). The vast majority of them are not experts in anything at all. Thus, you should treat what they say with as much respect as a stranger. You would not believe a 17 year old at Home Depot telling you about the latest Mars Rover photographs and its implication in the search for extraterrestrial life, would you? Why would it be believable if a DJ said what it implied? So basically, good idea asking in a forum that would be bound to have atleast a couple experts, or expert enough to answer correctly. People can't just bend science and math into their own wishes -- the math itself dictates what we can and can't do. And here, it says we should run. (BTW, I'm fairly sure walking would produce fewer kg/km CO2 and most of us are probably in better shape to walk 5 miles than run 5 miles).