The angle of incidence is the angle between the line perpendicular to the surface, and the incoming ray.
So, you should be able to figure out angle of incidence from the diagram...
Angle of reflection is always equal to angle of incidence (just on the other side of the perpendicular line). So that should take care of item 1.
Now, surely you've learned about Snell's law? n1*sin(theta1) = n2*sin(theta2) (this is the easiest form to remember for me -- sometimes textbooks list as as sin(theta1)/n2 = sin(theta2)/n1)
You can replace the "1"s above with incident, and the "2"s with refracted ... so n1 = 1 (air), n2 = 1.5 (glass), and theta1 = 30 degrees...Now just solve for theta2.
For total internal reflection to occur, when you try to solve the above equation, you would end up with sin(theta) > 1, which obviously can never happen. In this case, there is no refraction, only reflection.
If you look at the equation, it should be obvious that this can only happen when going from a higher index to a lower index -- such as going from glass to air, but never from air to glass.
Also, given the two indecies are fixed, the incident angle must be above a certain critical angle.
Assuming the slab of glass has parallel sides, then the original refracted ray (you calculated the angle in part 2) has the same angle of incidence onto the backside of the slab. So snell's law works in reverse, and you end up with a beam coming out the back that was parallel to the original beam, and no problem with TIR. If the slab was instead angled (more of a wedge than a slab), then TIR would be possible.
The critical angle for glass is found by solving snell's law where the refracted angle is just 90 degrees (sin theta=1).
Since we're going from glass to air, this would be solving 1.5*sin(theta_crit) = 1*sin(90) = 1
so the arcsine of (1/1.5).